{"created":"2023-06-19T07:00:05.067866+00:00","id":1267,"links":{},"metadata":{"_buckets":{"deposit":"24cb1b8a-a490-43f6-8fa6-311ef88d7790"},"_deposit":{"created_by":3,"id":"1267","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"1267"},"status":"published"},"_oai":{"id":"oai:rakuno.repo.nii.ac.jp:00001267","sets":["9:10:18:19"]},"author_link":["2898","2894","2896","2897","2893","2895","2892"],"item_2_biblio_info_9":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"Special Issue 1","bibliographicPageEnd":"15","bibliographicPageStart":"10","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"Dynamic Biochemistry, Process Biotechnology and Molecular Biology"}]}]},"item_2_description_43":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_description_6":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"This review focuses on the NMR methods for the oligosaccharides containing fructopyranoside that were previously isolated from the fermented beverage of an extract from 50 kinds of fruits and vegetables. The ^1H and ^<13>C-NMR signals of each saccharide were assigned using 2D-NMR including COSY, HSQC, HSQC-TOCSY, CH_2-selected HSQC-TOCSY, and CT (constant time)-HMBC. The fructose in pyranosyl form showed different ^<13>C chemical shifts from those of furanosyl form. Further confirmation of the pyranosyl form could be obtained from the HMBC correlation peak between C-2 and H-6 of fructose residue (Fru), whereas the C-2 of Fru in furanosyl form chould give the HMBC correlation peak between H-5 of Fru. Problems encountered were signal overlapping of protons and low peak separation. The key correlation peak between C-2 and H-6 of Fru was overlapped by the correlation peak indicating a glycosidic linkage between the C-2 of Fru and the H-6 of the glucose residue (Glc, or Glc’). These were solved using HSQC and CT-HMBC spectra rather than HMQC and conventional HMBC spectra, which have an inherent broad-line-shape in the carbon dimension.","subitem_description_type":"Abstract"}]},"item_2_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Global Science Books Ltd."}]},"item_2_rights_16":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"http://www.globalsciencebooks.info/Journals/DBPBMB.html | http://www.globalsciencebooks.info/Journals/DBPBMB.html"}]},"item_2_source_id_10":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1749-0626","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Fukushi, Eri"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okada, Hideki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamamori, Akira"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawazoe, Naoki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Onodera, Shuichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawabata, Jun"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shiomi, Norio"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-09-14"}],"displaytype":"detail","filename":"S-925_Onodera.pdf","filesize":[{"value":"405.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"S-925_Onodera.pdf","url":"https://rakuno.repo.nii.ac.jp/record/1267/files/S-925_Onodera.pdf"},"version_id":"b96a5384-f2dd-4bd7-93b2-a0ceeee14064"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"COSY","subitem_subject_scheme":"Other"},{"subitem_subject":"HSQC","subitem_subject_scheme":"Other"},{"subitem_subject":"HSQC-TOCSY","subitem_subject_scheme":"Other"},{"subitem_subject":"CH_2-selected HSQC-TOCSY","subitem_subject_scheme":"Other"},{"subitem_subject":"CT-HMBC","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"NMR Analysis of Oligosaccharides Containing Fructopyranoside","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"NMR Analysis of Oligosaccharides Containing Fructopyranoside"}]},"item_type_id":"2","owner":"3","path":["19"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-06-14"},"publish_date":"2011-06-14","publish_status":"0","recid":"1267","relation_version_is_last":true,"title":["NMR Analysis of Oligosaccharides Containing Fructopyranoside"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-19T09:09:14.410377+00:00"}