{"created":"2023-06-19T07:00:23.611311+00:00","id":1675,"links":{},"metadata":{"_buckets":{"deposit":"3d5263bc-ddb4-4998-a336-84850c942906"},"_deposit":{"created_by":3,"id":"1675","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"1675"},"status":"published"},"_oai":{"id":"oai:rakuno.repo.nii.ac.jp:00001675","sets":["9:10:23:24"]},"author_link":["3866","3613","3869","3868","3864","3867","3865","3863"],"item_2_biblio_info_9":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"383","bibliographicPageStart":"379","bibliographicVolumeNumber":"25","bibliographic_titles":[{"bibliographic_title":"Analytical Sciences"}]}]},"item_2_description_43":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_description_6":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Ion-exclusion chromatography was examined for the simultaneous spectrophotometric determinations of orthophosphate and silicate ions in river water using an ascorbate solution as both an eluent and a reducing agent, followed by postcolumn derivatization using molybdate. The detector responses for both ions increased with increased ascorbic acid concentration in the eluent, but peak tailing was observed for the orthophosphate ion. This suggests that the amounts of undissociated orthophosphate ions increased with decreased eluent pH, resulting in the penetration of the phosphate to the Donnan's membrane formed on the resin surface. Using a neutral sodium ascorbate solution as an eluent, the peak shape was improved. With optimized separation and derivatization conditions (eluent, 20 mM sodium ascorbate; color-forming reagent, 10 mM sodium molybdate-60 mM sulfuric acid; flow rates of eluent and color-forming reagent, 0.4 and 0.2 mL min^<-1>; coil length, 6 m), the detection limits of orthophosphate and silicate ions were 0.9 and 1.0 µg L^<-1>, respectively. This method was successfully applied to the determination of orthophosphate and silicate ions in Kurose River water and the quantitative evaluations of the effects of water intake to a reservoir and discharge from a biological sewage treatment plant on the fluxes of these ions in the river.","subitem_description_type":"Abstract"}]},"item_2_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_2_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.2116/analsci.25.379","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_10":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0910-6340","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":""}],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"NAKATANI, Nobutake","creatorNameLang":"en"},{"creatorName":"中谷, 暢丈","creatorNameLang":"ja"}],"familyNames":[{},{}],"givenNames":[{},{}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"MASUDA, Wakako"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"KOZAKI, Daisuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"GOTO, Ryozo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"NAKAGOSHI, Nobukazu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"MORI, Masanobu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"HASEBE, Kiyoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"TANAKA, Kazuhiko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-09-14"}],"displaytype":"detail","filename":"S-843_Nakatani.pdf","filesize":[{"value":"685.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"S-843_Nakatani.pdf","url":"https://rakuno.repo.nii.ac.jp/record/1675/files/S-843_Nakatani.pdf"},"version_id":"c2b1c3b4-1f03-48dc-a19c-9bd0d93b4fc1"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Simultaneous spectrophotometric determination of orthophosphate and silicate ions in river water using ion-exclusion chromatography with an ascorbate solution as both eluent and reducing agent, followed by postcolumn derivatization with molybdate","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Simultaneous spectrophotometric determination of orthophosphate and silicate ions in river water using ion-exclusion chromatography with an ascorbate solution as both eluent and reducing agent, followed by postcolumn derivatization with molybdate"}]},"item_type_id":"2","owner":"3","path":["24"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-03-31"},"publish_date":"2011-03-31","publish_status":"0","recid":"1675","relation_version_is_last":true,"title":["Simultaneous spectrophotometric determination of orthophosphate and silicate ions in river water using ion-exclusion chromatography with an ascorbate solution as both eluent and reducing agent, followed by postcolumn derivatization with molybdate"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-08-31T01:01:36.474138+00:00"}