{"created":"2023-06-19T07:02:56.454884+00:00","id":5150,"links":{},"metadata":{"_buckets":{"deposit":"140bd50b-164e-4285-b735-9b8388f75ee6"},"_deposit":{"created_by":3,"id":"5150","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5150"},"status":"published"},"_oai":{"id":"oai:rakuno.repo.nii.ac.jp:00005150","sets":["9:10:23:24"]},"author_link":["15972","15970","15969","15973","15971","3613"],"item_2_biblio_info_9":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"9-10","bibliographicPageStart":"9-1","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"Separations"}]}]},"item_2_description_43":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_description_6":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The simple and simultaneous determination of silicic, boric and carbonic acids was made using ion-exclusion chromatography (IEC) and a Corona^<TM> charged aerosol detector (C-CAD). Silicic and boric acids were separated by the column packed with a weakly acidic cation-exchange resin in H+-form and ultra-pure water eluent, and the detector responses were improved by the addition of acetonitrile to eluent. Under the optimized conditions, the simultaneous determination of weak inorganic acids, except for carbonic acid, was successfully performed. When the conversion column packed with a strong acidic cation-exchange resin in Na^+- or K^+-form was inserted between the separation column and the detector, weak inorganic acids including carbonic acid could be detected by the C-CAD. The calibration curves were linear in the range of 0.5-10 mg·L^<−1> as Si for silicic acid (r^2 = 0.996), 10–100 mg·L^<−1> as B for boric acid (r^2 = 0.998) and 1.3-21 mg·L^<−1> as C for carbonic acid (r^2 = 0.993). The detection limits based on three times the standard deviation were 0.03 mg·L^<−1> as Si for silicic acid, 0.40 mg·L^<−1> as B for boric acid and 0.08 mg·L^<−1> as C for carbonic acid. This method was applicable to river, hot spring and drinking water.","subitem_description_type":"Abstract"}]},"item_2_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"MDPI AG"}]},"item_2_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.3390/chromatography3010009","subitem_relation_type_select":"DOI"}}]},"item_2_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license"}]},"item_2_rights_16":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"https://creativecommons.org/licenses/by/4.0/ | https://creativecommons.org/licenses/by/4.0/"}]},"item_2_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Otsuka, Yu"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":""}],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"NAKATANI, Nobutake","creatorNameLang":"en"},{"creatorName":"中谷, 暢丈","creatorNameLang":"ja"}],"familyNames":[{},{}],"givenNames":[{},{}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Takahashi, Takuya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kozaki, Daisuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mori, Masanobu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Kazuhiko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-04-12"}],"displaytype":"detail","filename":"R-2017-50_Nakatani.pdf","filesize":[{"value":"599.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"R-2017-50_Nakatani.pdf","url":"https://rakuno.repo.nii.ac.jp/record/5150/files/R-2017-50_Nakatani.pdf"},"version_id":"fc8a52ba-ac8a-4acc-b933-01e8e57337f0"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ion-exclusion chromatography (IEC)","subitem_subject_scheme":"Other"},{"subitem_subject":"Corona^<TM> charged aerosol detector (C-CAD)","subitem_subject_scheme":"Other"},{"subitem_subject":"silicic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"boric acid","subitem_subject_scheme":"Other"},{"subitem_subject":"carbonic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"conversion column","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"The Simultaneous Determination of Silicic, Boric and Carbonic Acids in Natural Water via Ion-Exclusion Chromatography with a Charged Aerosol Detector","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The Simultaneous Determination of Silicic, Boric and Carbonic Acids in Natural Water via Ion-Exclusion Chromatography with a Charged Aerosol Detector"}]},"item_type_id":"2","owner":"3","path":["24"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-04-12"},"publish_date":"2018-04-12","publish_status":"0","recid":"5150","relation_version_is_last":true,"title":["The Simultaneous Determination of Silicic, Boric and Carbonic Acids in Natural Water via Ion-Exclusion Chromatography with a Charged Aerosol Detector"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-08-31T01:01:32.138536+00:00"}