{"created":"2023-06-19T07:03:22.918577+00:00","id":5661,"links":{},"metadata":{"_buckets":{"deposit":"46c3f4e4-0f47-4b23-ac1a-816dbcb3e6e6"},"_deposit":{"created_by":3,"id":"5661","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5661"},"status":"published"},"_oai":{"id":"oai:rakuno.repo.nii.ac.jp:00005661","sets":["9:10:18:19"]},"author_link":["2858","17863","17861","17862","17858","17859","17860","17857","2856"],"item_2_biblio_info_9":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"19","bibliographicPageStart":"15","bibliographicVolumeNumber":"64","bibliographic_titles":[{"bibliographic_title":"Journal of Applied Glycoscience"}]}]},"item_2_description_43":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_2_description_6":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The synthesis of the saccharide β-D-fructopyranosyl-(2→6)-D-glucopyranose, which was isolated from Super Ohtaka^®, has recently been reported. During the synthesis of this saccharide, the formation of two novel saccharides from D-glucose and D-fructose was observed. The present study aimed to confirm the structures of the two disaccharides synthesized from D-glucose and D-fructose by thermal treatment. Furthermore, various properties of the saccharides were investigated. Both saccharides were isolated from the reaction mixture by carbon-Celite column chromatography and an HPLC system and were determined to be novel sucrose-isomers, β-D-fructopyranosyl-(2↔1)-β-D-glucopyranoside (1) and β-D-fructofuranosyl-(2↔1)-β-D-glucopyranoside (2), by MALDI-TOF MS and NMR analyses. Both saccharides showed low digestibility in vitro, and the sweetness of saccharide 2 was 0.45 times that of sucrose.","subitem_description_type":"Abstract"}]},"item_2_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本応用糖質科学会"}]},"item_2_relation_11":{"attribute_name":"ISBN","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"1344-7882","subitem_relation_type_select":"ISBN"}}]},"item_2_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.5458/jag.jag.JAG-2016_011","subitem_relation_type_select":"DOI"}}]},"item_2_rights_16":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"https://creativecommons.org/licenses/by-nc/4.0/ | https://creativecommons.org/licenses/by-nc/4.0/"}]},"item_2_version_type_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamamori, Akira"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Takata, Yusuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fukushi, Eri"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawabata, Jun"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okada, Hideki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawazoe, Naoki"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":""}],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"上野, 敬司","creatorNameLang":""}],"familyNames":[{"familyNameLang":""}],"givenNames":[{"givenNameLang":""}],"nameIdentifiers":[{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":""}],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"小野寺, 秀一","creatorNameLang":""}],"familyNames":[{"familyNameLang":""}],"givenNames":[{"givenNameLang":""}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Shiomi, Norio"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-08-08"}],"displaytype":"detail","filename":"R-2018-70_ueno.pdf","filesize":[{"value":"428.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"R-2018-70_ueno.pdf","url":"https://rakuno.repo.nii.ac.jp/record/5661/files/R-2018-70_ueno.pdf"},"version_id":"49bc9e02-08d4-4084-8aaa-f46fe129e13a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"sucrose-isomer","subitem_subject_scheme":"Other"},{"subitem_subject":"disaccharide","subitem_subject_scheme":"Other"},{"subitem_subject":"thermal treatment","subitem_subject_scheme":"Other"},{"subitem_subject":"fermented beverage of plant extract","subitem_subject_scheme":"Other"},{"subitem_subject":"sucrose-isomer","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"disaccharide","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"thermal treatment","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"fermented beverage of plant extract","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Structural Analysis of Novel Low-Digestible Sucrose Isomers Synthesized from D-Glucose and D-Fructose by Thermal Treatment","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Structural Analysis of Novel Low-Digestible Sucrose Isomers Synthesized from D-Glucose and D-Fructose by Thermal Treatment"}]},"item_type_id":"2","owner":"3","path":["19"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-08-08"},"publish_date":"2019-08-08","publish_status":"0","recid":"5661","relation_version_is_last":true,"title":["Structural Analysis of Novel Low-Digestible Sucrose Isomers Synthesized from D-Glucose and D-Fructose by Thermal Treatment"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-08-31T00:56:52.873434+00:00"}